| Sex | Athlete | DOB | Discipline | Round | POS | Mark |
|---|---|---|---|---|---|---|
| M | Andrea DI CARLO | 31/01/2005 | 10 Kilometres Race Walk | Final | 30 | 42:58 |
| M | Alessio COPPOLA | 25/01/2007 | 10 Kilometres Race Walk | Final | 28 | 42:45 |
| M | Giuseppe DISABATO | 01/11/2006 | 10 Kilometres Race Walk | Final | 5 | 40:32 |
| W | Serena DI FABIO | 23/11/2007 | 10 Kilometres Race Walk | Final | 7 | 46:12 |
| W | Michelle CANTÒ | 14/07/2005 | 10 Kilometres Race Walk | Final | 9 | 46:27 |
| W | Giulia GABRIELE | 11/11/2005 | 10 Kilometres Race Walk | Final | 4 | 45:26 |
| W | Eleonora Anna GIORGI | 14/09/1989 | 20 Kilometres Race Walk | Final | DQ | |
| W | Alexandrina MIHAI | 27/05/2003 | 20 Kilometres Race Walk | Final | 22 | 1:33:19 |
| W | Nicole COLOMBI | 29/12/1995 | 20 Kilometres Race Walk | Final | 28 | 1:35:24 |
| W | Federica CURIAZZI | 14/08/1992 | 20 Kilometres Race Walk | Final | 16 | 1:32:32 |
| W | Eleonora DOMINICI | 22/02/1996 | 20 Kilometres Race Walk | Final | 25 | 1:34:48 |
| M | Emiliano BRIGANTE | 27/05/2003 | 20 Kilometres Race Walk | Final | 33 | 1:22:59 |
| M | Riccardo ORSONI | 20/01/2000 | 20 Kilometres Race Walk | Final | 7 | 1:20:11 |
| M | Andrea AGRUSTI | 30/08/1995 | 20 Kilometres Race Walk | Final | 32 | 1:22:52 |
| M | Michele ANTONELLI | 23/05/1994 | 20 Kilometres Race Walk | Final | 14 | 1:21:18 |
| M | Gianluca PICCHIOTTINO | 22/08/1996 | 20 Kilometres Race Walk | Final | 12 | 1:21:06 |
| X | Italy | Marathon Race Walk Mixed Relay | Final | DNF | ||
| X | Italy 2 | Marathon Race Walk Mixed Relay | Final | 1 | 2:56:45 |