| M | Filip KRESTIANKO | 13/12/2005 | 10 Kilometres Race Walk | Final | 27 | 42:40 |
| M | Lukáš ROSENBAUM | 25/07/2007 | 10 Kilometres Race Walk | Final | 47 | 46:41 |
| M | Jakub BÁTOVSKÝ | 18/06/2005 | 10 Kilometres Race Walk | Final | 32 | 43:29 |
| W | Ivana DUDOVÁ | 08/06/2005 | 10 Kilometres Race Walk | Final | 41 | 51:38 |
| W | Tamara INDRIŠKOVÁ | 25/05/2006 | 10 Kilometres Race Walk | Final | 38 | 50:43 |
| W | Kristína ZÁMECNIKOVA | 27/09/2007 | 10 Kilometres Race Walk | Final | 36 | 49:53 |
| W | Ema HAČUNDOVÁ | 05/03/1999 | 20 Kilometres Race Walk | Final | 41 | 1:39:47 |
| W | Karin DEVALDOVÁ | 12/07/2003 | 20 Kilometres Race Walk | Final | 63 | 1:56:27 |
| W | Klaudia ŽÁRSKA | 15/06/1999 | 20 Kilometres Race Walk | Final | 57 | 1:47:44 |
| W | Alžbeta RAGASOVÁ | 06/04/2002 | 20 Kilometres Race Walk | Final | | DQ |
| M | Michal MORVAY | 19/08/1996 | 20 Kilometres Race Walk | Final | 49 | 1:25:47 |
| X | Slovak Republic | | Marathon Race Walk Mixed Relay | Final | 21 | 3:05:38 |
| X | Slovak Republic 2 | | Marathon Race Walk Mixed Relay | Final | 24 | 3:06:11 |