First 2 in each heat (Q) and the next 2 fastest (q)
| POS | Rank | Heat | BIB | ATHLETE | COUNTRY | RESULTS |
|---|---|---|---|---|---|---|
| 1 | 1 | 4 | 529 | Natallia Safronnikava |
 BLR |
23.03 Q SB |
| 2 | 1 | 2 | 747 | Svetlana Goncharenko |
 RUS |
23.08 Q SB |
| 3 | 1 | 749 | Anastasiya Kapachinskaya |
RUS |
DQ Q | |
| 4 | 2 | 809 | Crystal Cox |
 USA |
DQ | |
| 5 | 2 | 4 | 799 | Maryna Maydanova |
 UKR |
23.34 Q |
| 6 | 3 | 4 | 774 | Alenka Bikar |
 SLO |
23.36 q SB |
| 7 | 1 | 3 | 508 | Karin Mayr-Krifka |
 AUT |
23.38 Q |
| 8 | 1 | 1 | 804 | Nataliia Pygyda |
UKR |
23.39 Q |
| 9 | 2 | 3 | 681 | Juliet Campbell |
 JAM |
23.51 Q |
| 10 | 3 | 3 | 807 | Rachelle Boone-Smith |
USA |
23.59 q |
| 11 | 2 | 2 | 658 | Nikolett Listár |
 HUN |
23.71 PB |
| 12 | 3 | 2 | 601 | Johanna Manninen |
 FIN |
23.79 |
| 13 | 2 | 1 | 666 | Ciara Sheehy |
 IRL |
23.86 |
| 14 | 3 | 1 | 698 | Gretta Taslakian |
 LIB |
25.80 NR |
| 15 | 4 | 3 | 664 | Yulia Novita Novita |
 INA |
26.69 NR |
| 4 | 636 | Vida Anim |
 GHA |
DNS |